Analytical figures of merit : from univariate to multi-way calibration

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dc.citation.titleChemical Reviews
dc.citation.volume114(10)
dc.creatorOlivieri, Alejandro César
dc.date.accessioned2018-02-02T14:24:57Z
dc.date.available2018-02-02T14:24:57Z
dc.date.issued2014-03-19
dc.descriptionThe search for new ways to improve analytical figures of merit is an important driving force in modern analytical chemistry research, with the sensitivity occupying one of the prominent places among these figures. Whether the purpose is the comparison of the performance of different experimental procedures or the optimization of a given methodology under various experimental conditions, a consistent numerical sensitivity parameter is required in order to judge about the real improvement obtained from various experimental strategies. Analytical figures of merit are an integral part of official protocols of analysis, as documented in international standards. The International Union of Pure and Applied Chemistry (IUPAC) has set sensitivity definitions for various calibration scenarios. What is even more worrying, the plainly extrapolated expressions to data arrays with higher number of modes appeared to lead to a serious underestimation of true sensitivities.es
dc.description.filFil: Olivieri, Alejandro César. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Departamento de Química Analítica. Instituto de Química de Rosario (IQUIR-CONICET); Argentina.
dc.description.sponsorshipUniversidad Nacional de Rosarioes
dc.description.sponsorshipConsejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Project No. PIP 1950es
dc.description.sponsorshipAgencia Nacional de Promoción Científica y Tecnológica (ANPCyT), Project No. PICT-2010-0084es
dc.formatapplication/pdf
dc.format.extent5358–5378
dc.identifier.issn0009-2665
dc.identifier.urihttp://hdl.handle.net/2133/10490
dc.language.isoenges
dc.publisherAmerican Chemical Societyes
dc.relation.publisherversionhttp://pubs.acs.org/doi/ipdf/10.1021/cr400455ses
dc.relation.publisherversionhttps://doi.org/10.1021/cr400455ses
dc.rightsopenAccesses
dc.rights.holderOlivieri, Alejandro Césares
dc.rights.holderUniversidad Nacional de Rosarioes
dc.rights.holderAmerican Chemical Societyes
dc.rights.textAttribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.rights.urihttp://creativecommons.org/licenses/by-nc-sa/2.5/ar/*
dc.subjectMultivariate Calibration with ANNes
dc.subjectFigures of Merites
dc.subjectGrain Quality Controles
dc.titleAnalytical figures of merit : from univariate to multi-way calibrationes
dc.typepublishedVersion

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