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Eco-friendly methoximation of aromatic aldehydes and ketones using MnCl 2.4H 2 O as an easily accessible and efficient catalyst

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Eco-friendly methoximation of aromatic aldehydes and ketones using MnCl 2.4H 2 O as an easily accessible and efficient catalyst.pdf (2,17 MB)

Fecha

2021

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Editor

The Royal Society

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Descripción

Methoximes are important as a class of intermediates and products, among fine chemicals and specialties. The development of a new, facile and efficient method for their synthesis is reported. The methoximes were properly accessed from the corresponding aromatic aldehydes and ketones in good to excellent yields, under mild conditions, employing the inexpensive and environmentally friendly MnCl2.4H2O as a catalyst (at low loading and without the addition of ligand), in EtOH at 50°C. The scope of the process was systematically assessed.

Palabras clave

Eco-conscious reaction, Methoximation of aldehydes and ketones, MnCl2-catalysed transformation

Citación

URI

http://hdl.handle.net/2133/23091

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(FBIOyF) Departamento de Química Orgánica - Artículos

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Licencia Creative Commons

Attribution 4.0 International (CC BY 4.0)
Excepto donde se indique lo contrario, la licencia de este ítem se describe como Attribution 4.0 International (CC BY 4.0)