Gold-catalyzed addition of β-ketoesters to alkenes: influence of electronic and steric effects in the reaction outcome

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dc.citation.titleMoleculeses
dc.citation.volume23(3)es
dc.creatorLa Venia, Agustina
dc.creatorMischne, Mirta P.
dc.creatorMata, Ernesto Gabino
dc.date.accessioned2020-12-18T00:09:29Z
dc.date.available2020-12-18T00:09:29Z
dc.date.issued2018-03-10
dc.descriptionThe gold-catalyzed intermolecular hydroalkylation of olefins with β-ketoesters represents a conceptually attractive and useful synthetic tool; however, it has been scarcely applied, remaining a challenge for chemists. The aim of the current study was to investigate the addition of these 1,3-diketo-compounds to alkenes under gold catalysis conditions, in order to establish the electronic and steric effects of the alkenyl substrates in the reaction outcome. The screening of different catalyst systems and diverse olefins enabled defining the alkenyl requirements and the best reaction conditions to efficiently achieve the coupled products.es
dc.descriptionPara citar este articulo: La-Venia, A.; Mischne, M.P.; Mata, E.G. Gold-Catalyzed Addition of β-Ketoesters to Alkenes: Influence of Electronic and Steric Effects in the Reaction Outcome. Molecules 2018, 23, 629.
dc.description.filFil: La Venia, Agustina. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario (IQUIR -CONICET); Argentina.es
dc.description.filFil: Mischne, Mirta P. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario (IQUIR -CONICET); Argentina.es
dc.description.filFil: Mata, Ernesto Gabino. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario (IQUIR -CONICET); Argentina.es
dc.description.sponsorshipConsejo Nacional de Investigaciones Científicas y Técnicas de Argentina (CONICET)es
dc.description.sponsorshipAgencia Nacional de Promoción Científica y Tecnológica (ANPCyT)es
dc.description.sponsorshipUniversidad Nacional de Rosario (UNR)es
dc.formatapplication/pdf
dc.format.extent1-11es
dc.identifier.issn1420-3049es
dc.identifier.urihttp://hdl.handle.net/2133/19506
dc.language.isoenges
dc.publisherMDPIes
dc.relation.publisherversionhttps://doi.org/10.3390/molecules23030629es
dc.relation.publisherversionhttps://www.mdpi.com/1420-3049/23/3/629es
dc.rightsopenAccesses
dc.rights.holderUniversidad Nacional de Rosarioes
dc.rights.holderLa Venia, Agustinaes
dc.rights.holderMischne, Mirta P.es
dc.rights.holderMata, Ernesto Gabinoes
dc.rights.textAttribution 4.0 International (CC BY 4.0)es
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/*
dc.subjectCatalysises
dc.subjectGoldes
dc.subjectHydroalkylationes
dc.subjectbeta-Ketoesterses
dc.subjectAlkeneses
dc.titleGold-catalyzed addition of β-ketoesters to alkenes: influence of electronic and steric effects in the reaction outcomees
dc.typearticle
dc.typeartículo
dc.typepublishedVersion
dc.type.collectionarticulo
dc.type.versionpublishedVersiones

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