Unprecedented multifunctionality of Grubbs and Hoveyda–Grubbs catalysts: competitive isomerization, hydrogenation, silylation and metathesis occurring in solution and on solid phase

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dc.citation.titleCatalystses
dc.citation.volume7(4)es
dc.creatorMartínez Amezaga, Maitena
dc.creatorDelpiccolo, Carina M. L.
dc.creatorMéndez, Luciana
dc.creatorDragutan, Ileana
dc.creatorDragutan, Valerian
dc.creatorMata, Ernesto Gabino
dc.date.accessioned2020-12-17T01:36:46Z
dc.date.available2020-12-17T01:36:46Z
dc.date.issued2017-04-09
dc.descriptionThis contribution showcases the interplay of several non-metathetic reactions (isomerization, silylation and “hydrogen-free” reduction) with metathesis in systems comprising a functionalized olefin and a soluble or resin-immobilized silane. These competing, one-pot reactions occur under activation by second generation Ru-alkylidene catalysts. Different olefinic substrates were used to study the influence of the substitution pattern on the reaction outcome. Emphasis is placed upon the rarely reported yet important transformations implying a solid phase-supported silane reagent. Catalytic species involved in and reaction pathways accounting for these concurrent processes are evidenced. An unexpected result of this research was the clearly proved partial binding of the olefin to the resin, thereby removing it from the reacting ensemble.es
dc.description.filFil: Martínez Amezaga, Maitena. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario (IQUIR -CONICET); Argentina.es
dc.description.filFil: Delpiccolo, Carina M. L. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario (IQUIR -CONICET); Argentina.es
dc.description.filFil: Méndez, Luciana. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario (IQUIR -CONICET); Argentina.es
dc.description.filFil: Dragutan, Ileana. Romanian Academy. Institute of Organic Chemistry; Romania.es
dc.description.filFil: Dragutan,Valerian. Romanian Academy. Institute of Organic Chemistry; Romania.es
dc.description.filFil: Mata, Ernesto Gabino. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario (IQUIR -CONICET); Argentina.es
dc.description.sponsorshipConsejo Nacional de Investigaciones Científicas y Técnicas (CONICET)es
dc.description.sponsorshipAgencia Nacional de Promoción Científica y Tecnológica (ANPCyT)es
dc.description.sponsorshipUniversidad Nacional de Rosario (UNR)es
dc.description.sponsorshipInstitute of Organic Chemistry "C. D. Nenitescu" of Romanian Academyes
dc.formatapplication/pdf
dc.format.extent1-14es
dc.identifier.issn2073-4344es
dc.identifier.urihttp://hdl.handle.net/2133/19494
dc.language.isoenges
dc.publisherMDPIes
dc.relation.publisherversionhttps://doi.org/10.3390/catal7040111es
dc.relation.publisherversionhttps://www.mdpi.com/2073-4344/7/4/111es
dc.rightsopenAccesses
dc.rights.holderUniversidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticases
dc.rights.holderMartínez Amezaga, Maitenaes
dc.rights.holderDelpiccolo, Carina M. L.es
dc.rights.holderMéndez, Lucianaes
dc.rights.holderDragutan, Ileanaes
dc.rights.holderDragutan, Valerianes
dc.rights.holderMata, Ernesto Gabinoes
dc.rights.textAttribution 4.0 International (CC BY 4.0)es
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/*
dc.subjectCross-metathesises
dc.subjectReductiones
dc.subjectSilylationes
dc.subjectIsomerizationes
dc.subjectSolid-phasees
dc.subjectAlkeneses
dc.subjectRuthenium Catalystes
dc.titleUnprecedented multifunctionality of Grubbs and Hoveyda–Grubbs catalysts: competitive isomerization, hydrogenation, silylation and metathesis occurring in solution and on solid phasees
dc.typearticle
dc.typeartículo
dc.typepublishedVersion
dc.type.collectionarticulo
dc.type.versionpublishedVersiones

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