Examinando por Autor "Pisano, Pablo Luis"
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Ítem Acceso Abierto Alkylhalovinylboranes: a new class of Diels-Alder dienophiles(Royal Society of Chemistry, 2018-10-02) Pisano, Pablo Luis; Pellegrinet, Silvina Carla; https://orcid.org/0000-0002-6368-9234; https://orcid.org/0000-0001-6854-7377The Diels–Alder reactions of alkylhalovinylboranes have been investigated theoretically and experimentally. Alkylhalovinylboranes presented higher reactivity than the corresponding dialkylvinylboranes. Although endo/exo selectivities were high for the reactions with cyclopentadiene, facial selectivities for the chiral analogues were low. Our results demonstrate that the replacement of an alkyl group on the boron atom by a halogen increases the dienophilicity considerably.Ítem Acceso Abierto Discrimination of Annona muricata and Rollinia mucosa extracts by using multivariate curve resolution and partial least-squares regression of liquid chromatography-diode array data(Brazilian Chemical Society, 2015-11) Afonso, Sabrina; Pisano, Pablo Luis; Silva, Fabiano; Scaminio, Ieda; Olivieri, Alejandro CésarÍtem Acceso Abierto Exploration of liquid chromatographic-diode array data for Argentinean wines by extended multivariate curve resolution(Elsevier, 2014-03-15) Pisano, Pablo Luis; Silva, María Fernanda; Olivieri, Alejandro César