Eco-friendly methoximation of aromatic aldehydes and ketones using MnCl 2.4H 2 O as an easily accessible and efficient catalyst

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dc.creator Ontivero, Melina C.
dc.creator Kaufman, Teodoro Saúl
dc.creator Cortés, Iván
dc.creator Bracca, Andrea Beatriz Juana
dc.date.accessioned 2022-02-21T19:15:40Z
dc.date.available 2022-02-21T19:15:40Z
dc.date.issued 2021
dc.identifier.issn 2054-5703 es
dc.identifier.uri http://hdl.handle.net/2133/23091
dc.description Methoximes are important as a class of intermediates and products, among fine chemicals and specialties. The development of a new, facile and efficient method for their synthesis is reported. The methoximes were properly accessed from the corresponding aromatic aldehydes and ketones in good to excellent yields, under mild conditions, employing the inexpensive and environmentally friendly MnCl2.4H2O as a catalyst (at low loading and without the addition of ligand), in EtOH at 50°C. The scope of the process was systematically assessed. es
dc.description.sponsorship Secretaría de Ciencia y Tecnología. Universidad Nacional de Rosario (SECyT-UNR)
dc.description.sponsorship Consejo Nacional de Investigadores Científicas y Técnicas (CONICET)
dc.description.sponsorship Instituto de Química Rosario (IQUIR)
dc.format application/pdf
dc.format.extent 1-12 es
dc.language.iso eng es
dc.publisher The Royal Society es
dc.rights openAccess es
dc.rights.uri https://creativecommons.org/licenses/by/4.0/ *
dc.subject Eco-conscious reaction es
dc.subject Methoximation of aldehydes and ketones es
dc.subject MnCl2-catalysed transformation es
dc.title Eco-friendly methoximation of aromatic aldehydes and ketones using MnCl 2.4H 2 O as an easily accessible and efficient catalyst es
dc.type article
dc.type artículo
dc.type publishedVersion
dc.rights.holder Ontivero, Melina es
dc.rights.holder Kaufman, Teodoro Saúl es
dc.rights.holder Cortés, Iván es
dc.rights.holder Bracca, Andrea Beatriz Juana es
dc.relation.publisherversion https://doi.org/10.1098/rsos.210142
dc.relation.publisherversion https://royalsocietypublishing.org/doi/10.1098/rsos.210142
dc.rights.text Attribution 4.0 International (CC BY 4.0) es
dc.citation.title Royal Society Open Science es
dc.description.fil Fil: Ontivero, Melina C. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas; Argentina. es
dc.description.fil Fil: Ontivero, Melica C. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario (IQUIR-CONICET); Argentina. es
dc.description.fil Fil: Kaufman, Teodoro Saúl. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas; Argentina. es
dc.description.fil Fil: Kaufman, Teodoro Saúl. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario (IQUIR-CONICET); Argentina. es
dc.description.fil Fil: Cortés, Iván. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas; Argentina. es
dc.description.fil Fil: Cortés, Iván. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario (IQUIR-CONICET); Argentina. es
dc.description.fil Fil: Bracca, Andrea Beatriz Juana. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas; Argentina. es
dc.description.fil Fil: Bracca, Andrea Beatriz Juana. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario (IQUIR-CONICET); Argentina. es
dc.type.collection articulo
dc.type.version publishedVersion es


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