Analytical figures of merit : from univariate to multi-way calibration

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dc.creator Olivieri, Alejandro César
dc.date.accessioned 2018-02-02T14:24:57Z
dc.date.available 2018-02-02T14:24:57Z
dc.date.issued 2014-03-19
dc.identifier.issn 0009-2665
dc.identifier.uri http://hdl.handle.net/2133/10490
dc.description The search for new ways to improve analytical figures of merit is an important driving force in modern analytical chemistry research, with the sensitivity occupying one of the prominent places among these figures. Whether the purpose is the comparison of the performance of different experimental procedures or the optimization of a given methodology under various experimental conditions, a consistent numerical sensitivity parameter is required in order to judge about the real improvement obtained from various experimental strategies. Analytical figures of merit are an integral part of official protocols of analysis, as documented in international standards. The International Union of Pure and Applied Chemistry (IUPAC) has set sensitivity definitions for various calibration scenarios. What is even more worrying, the plainly extrapolated expressions to data arrays with higher number of modes appeared to lead to a serious underestimation of true sensitivities. es
dc.description.sponsorship Universidad Nacional de Rosario es
dc.description.sponsorship Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Project No. PIP 1950 es
dc.description.sponsorship Agencia Nacional de Promoción Científica y Tecnológica (ANPCyT), Project No. PICT-2010-0084 es
dc.format application/pdf
dc.format.extent 5358–5378
dc.language.iso eng es
dc.publisher American Chemical Society es
dc.rights openAccess es
dc.rights.uri http://creativecommons.org/licenses/by-nc-sa/2.5/ar/ *
dc.subject Multivariate Calibration with ANN es
dc.subject Figures of Merit es
dc.subject Grain Quality Control es
dc.title Analytical figures of merit : from univariate to multi-way calibration es
dc.rights.holder Olivieri, Alejandro César es
dc.rights.holder Universidad Nacional de Rosario es
dc.rights.holder American Chemical Society es
dc.relation.publisherversion http://pubs.acs.org/doi/ipdf/10.1021/cr400455s es
dc.relation.publisherversion doi:10.1021/cr400455s es
dc.citation.title Chemical Reviews
dc.citation.volume 114(10)
dc.description.fil Fil: Olivieri, Alejandro César. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Departamento de Química Analítica. Instituto de Química de Rosario (IQUIR-CONICET); Argentina.


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